Anbreina
konposatu kimiko
Anbreina konposatu organikoa da, C30H52O formula duena, triterpenoen familiakoa. Ez du usainik. Kaxaloteen koprolitoa den anbar grisaren osagaietako bat da[1].
Anbreina | |
---|---|
Formula kimikoa | C30H52O |
SMILES kanonikoa | 2D eredua |
SMILES isomerikoa | C=C1CCCC(C)(C)[C@@H]1CC/C(C)=C/CC[C@@H]1[C@@]2(C)CCCC(C)(C)[C@@H]2CC[C@@]1(C)O |
MolView | 3D eredua |
Mota | (4aR/S)-ambrein (en) eta [[1-[6-(2,2-Dimethyl-6-methylidenecyclohexyl)-4-methylhex-3-en-1-yl]-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol|1-[6-(2,2-Dimethyl-6-methylidenecyclohexyl)-4-methylhex-3-en-1-yl]-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol]] (en) |
Estereoisomeroa | [[(1R,2R,4aS,8aS)-1-[6-[(1S)-2,2-dimethyl-6-methylidenecyclohexyl]-4-methylhex-3-enyl]-2,5,5,8a-tetramethyl-3,4,4a,6,7,8-hexahydro-1H-naphthalen-2-ol|(1R,2R,4aS,8aS)-1-[6-[(1S)-2,2-dimethyl-6-methylidenecyclohexyl]-4-methylhex-3-enyl]-2,5,5,8a-tetramethyl-3,4,4a,6,7,8-hexahydro-1H-naphthalen-2-ol]] (en) eta [[(1R,2R,4aS,8aR)-1-[(E)-6-[(1S)-2,2-dimethyl-6-methylidenecyclohexyl]-4-methylhex-3-enyl]-2,5,5,8a-tetramethyl-3,4,4a,6,7,8-hexahydro-1H-naphthalen-2-ol|(1R,2R,4aS,8aR)-1-[(E)-6-[(1S)-2,2-dimethyl-6-methylidenecyclohexyl]-4-methylhex-3-enyl]-2,5,5,8a-tetramethyl-3,4,4a,6,7,8-hexahydro-1H-naphthalen-2-ol]] (en) |
Masa molekularra | 428,401816284 Da |
Identifikatzaileak | |
InChlKey | BIADSXOKHZFLSN-RMCJHQKMSA-N |
CAS zenbakia | 473-03-0 |
PubChem | 12305858 |
EC zenbakia | 207-460-3 |
ECHA | 100.006.784 |
CosIng | 39024 |
UNII | 1N9JB373FJ |
Kaxalotearen koprolitoa itsasora iristen denean oxidazio-prozesu bat pairatzen du atmosferako oxigenoa, itsasoko ura eta tenperatura medio. Prozesu horretan usainik ez duen anbreina eraldatu egiten da anbroxido bihurtuta. Molekula horixe da, hain zuzen ere, anbarrari usaina ematen diona, perfumegintzan horren preziatua dena[2].
Anbreina afrodisiako eta analgesiko gisa jo izan da[3][4][5].
Erreferentziak
aldatu- ↑ (Ingelesez) PubChem. «Ambrein» pubchem.ncbi.nlm.nih.gov (Noiz kontsultatua: 2024-08-24).
- ↑ Iruin, Yanko. (viernes, 23 de agosto de 2024). «La síntesis del sutil aroma del ámbar gris» EL BLOG DEL BÚHO (Noiz kontsultatua: 2024-08-24).
- ↑ (Ingelesez) Sandroni, Paola. (2001-10-01). «Aphrodisiacs past and present: A historical review» Clinical Autonomic Research 11 (5): 303–307. doi: . ISSN 1619-1560. (Noiz kontsultatua: 2024-08-24).
- ↑ Taha, S. A.; Islam, M. W.; Ageel, A. M.. (1995). «Effect of ambrein, a major constituent of ambergris, on masculine sexual behavior in rats» Archives Internationales De Pharmacodynamie Et De Therapie 329 (2): 283–294. ISSN 0003-9780. PMID 8540767. (Noiz kontsultatua: 2024-08-24).
- ↑ Taha, S. A; Raza, M; El-Khawad, I. E. (1998-02-01). «Effect of ambrein on smooth muscle responses to various agonists» Journal of Ethnopharmacology 60 (1): 19–26. doi: . ISSN 0378-8741. (Noiz kontsultatua: 2024-08-24).