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|colspan=4 bgcolor="#cccccc" | '''Round 1 – 13 March 2014'''
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|Dmitry Andreikin || Vladimir Kramnik ||align=center width="30px"| ½–½ || E32 [[Nimzo-Indian Defence#Classical Variation .28or Capablanca Variation.29 4.Qc2|Nimzo-Indian, Classical]]
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|Sergey Karjakin || Peter Svidler ||align=center | ½–½ || B48 [[Sicilian Defence#Taimanov Variation: 4...Nc6|Sicilian, Taimanov]]
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|Shakhriyar Mamedyarov || Veselin Topalov ||align=center | ½–½ || D11 [[Slav Defense#Main Line.2C Slav Accepted|Slav Accepted]]
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|Viswanathan Anand || Levon Aronian ||align=center | 1–0 || C88 [[Ruy Lopez#Marshall Attack: 7...0-0 8.c3 d5|Ruy Lopez]]
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|colspan=4 bgcolor="#cccccc" | '''Round 2 – 14 March 2014'''
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|Vladimir Kramnik (½) || Sergey Karjakin (½) ||align=center | 1–0 || D20 [[Queen's Gambit Accepted]]
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| Peter Svidler (½) || Dmitry Andreikin (½) ||align=center | 1–0 || B32 [[Sicilian Defence#Kalashnikov Variation: 4...e5 5. Nb5 d6|Sicilian Defence]]
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| Veselin Topalov (½) || Viswanathan Anand (1) ||align=center | ½–½ || A11 [[English Opening]]
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| Levon Aronian (0) || Shakhriyar Mamedyarov (½) ||align=center | 1–0 || D38 [[Queen's Gambit Declined]]
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|colspan=4 bgcolor="#cccccc" | '''Round 3 – 15 March 2014'''
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|Dmitry Andreikin (½) || Sergey Karjakin (½) ||align=center | ½–½ || C65 [[Ruy Lopez#Berlin Defence: 3...Nf6|Ruy Lopez, Berlin Defence]]
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| Peter Svidler (1½) || Vladimir Kramnik (1½) ||align=center | ½–½ || A35 [[English Opening#1...c5|English, Symmetrical]]
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| Veselin Topalov (1) || Levon Aronian (1) ||align=center | ½–½ || C88 [[Ruy Lopez]]
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| Shakhriyar Mamedyarov (½) || Viswanathan Anand (1½) ||align=center | 0–1 || D11 [[Slav Defense#Main Line.2C Slav Accepted|Slav Accepted]]
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|colspan=4 bgcolor="#cccccc" | '''Round 4 – 17 March 2014'''
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| Shakhriyar Mamedyarov (½) || Dmitry Andreikin (1) ||align=center | 1–0 || D45 [[Queen's Gambit Declined|Queen's Gambit Declined Semi-Slav]]
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| Sergey Karjakin (1) || Veselin Topalov (1½) ||align=center | ½–½ || A29 [[English Opening#Reversed Sicilian: 1...e5|English, Four Knights, Kingside Fianchetto]]
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| Levon Aronian (1½) || Peter Svidler (2) ||align=center | 1–0 || D85 [[Grünfeld Defence#Exchange Variation|Grünfeld, Exchange]]
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| Viswanathan Anand (2½) || Vladimir Kramnik (2) ||align=center | ½–½ || D37 [[Queen's Gambit Declined]]
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|colspan=4 bgcolor="#cccccc" | '''Round 5 – 18 March 2014'''
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| Dmitry Andreikin (1) || Viswanathan Anand (3) ||align=center | ½–½ || C65 [[Ruy Lopez#Berlin Defence: 3...Nf6|Ruy Lopez, Berlin Defence]]
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| Sergey Karjakin (1½) || Shakhriyar Mamedyarov (1½) ||align=center | ½–½ || B52 [[Sicilian Defence#2.Nf3 without 3.d4: White.27s third move alternatives|Sicilian Defence, Canal-Sokolsky Attack]]
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| Peter Svidler (2) || Veselin Topalov (2) ||align=center | 1–0 || C78 [[Ruy Lopez]]
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| Vladimir Kramnik (2½) || Levon Aronian (2½) ||align=center | ½–½ || E10 [[Queen's Pawn Game]]
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|colspan=4 bgcolor="#cccccc" | '''Round 6 – 19 March 2014'''
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| Levon Aronian (3) || Dmitry Andreikin (1½) ||align=center | ½–½ || A12 [[English Opening#1...c6|English, Caro-Kann Defensive System]]
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| Viswanathan Anand (3½) || Sergey Karjakin (2) ||align=center | ½–½ || C67 [[Ruy Lopez#Berlin Defence: 3...Nf6|Ruy Lopez, Berlin Defence, Open Variation]]
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| Shakhriyar Mamedyarov (2) || Peter Svidler (3) ||align=center | 1–0 || A81 [[Dutch Defence]]
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| Veselin Topalov (2) || Vladimir Kramnik (3) ||align=center | 1–0 || D37 [[Queen's Gambit Declined]]
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|colspan=4 bgcolor="#cccccc" | '''Round 7 – 21 March 2014'''
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| Sergey Karjakin (2½) || Levon Aronian (3½) ||align=center | 0–1 || C65 [[Ruy Lopez#Berlin Defence: 3...Nf6|Ruy Lopez, Berlin Defence]]
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| Peter Svidler (3) || Viswanathan Anand (4) ||align=center | ½–½ || C65 [[Ruy Lopez#Berlin Defence: 3...Nf6|Ruy Lopez, Berlin Defence]]
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|Vladimir Kramnik (3) || Shakhriyar Mamedyarov (3) ||align=center | 1–0 || D38 [[Queen's Gambit Declined]]
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| Dmitry Andreikin (2) || Veselin Topalov (3) ||align=center | 1–0 || D30 [[Queen's Gambit Declined]]
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|}
|colspan=4 bgcolor="#cccccc" | '''Round 8 – 22 March 2014'''
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| Vladimir Kramnik (4) || Dmitry Andreikin (3) ||align=center width="30px" | ½–½ || D15 [[Queen's Gambit Declined Slav]]
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| Peter Svidler (3½) || Sergey Karjakin (2½) ||align=center | 0–1 || A05 [[Réti Opening]]
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| Veselin Topalov (3) || Shakhriyar Mamedyarov (3) ||align=center | ½–½ || B90 [[Sicilian Defence, Najdorf Variation]]
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| Levon Aronian (4½) || Viswanathan Anand (4½) ||align=center | ½–½ || A11 [[English Opening#1...c6|English, Caro-Kann Defensive System]]
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|colspan=4 bgcolor="#cccccc" | '''Round 9 – 23 March 2014'''
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| Sergey Karjakin (3½) || Vladimir Kramnik (4½) ||align=center | 1–0 || D02 [[Queen's Pawn Game]]
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| Dmitry Andreikin (3½) || Peter Svidler (3½) ||align=center | ½–½ || B90 [[Sicilian Defence, Najdorf Variation]]
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| Viswanathan Anand (5) || Veselin Topalov (3½) ||align=center | 1–0 || B90 [[Sicilian Defence, Najdorf Variation]]
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| Shakhriyar Mamedyarov (3½) || Levon Aronian (5) ||align=center | 1–0 || E20 [[Nimzo-Indian]]
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|colspan=4 bgcolor="#cccccc" | '''Round 10 – 25 March 2014'''
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| Sergey Karjakin (4½) || Dmitry Andreikin (4) ||align=center | ½–½ || B46 [[Sicilian_DefenceSicilian Defence#Taimanov_VariationTaimanov Variation:_4 4...Nc6|Sicilian Defence, Taimanov Variation]]
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| Vladimir Kramnik (4½) || Peter Svidler (4) ||align=center | 0–1 || A80 [[Dutch Defense]]
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| Levon Aronian (5) || Veselin Topalov (3½) ||align=center | ½–½ || D15 [[Queen's Gambit Declined Slav]]
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| Viswanathan Anand (6) || Shakhriyar Mamedyarov (4½) ||align=center | ½–½ || B90 [[Sicilian Defence, Najdorf Variation]]
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|colspan=4 bgcolor="#cccccc" | '''Round 11 – 26 March 2014'''
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| Dmitry Andreikin (4½) || Shakhriyar Mamedyarov (5) ||align=center | ½–½ || E04 [[Catalan Opening|Catalan Opening, Open, 5. Nf3]]
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| Veselin Topalov (4) || Sergey Karjakin (5) ||align=center | ½–½ || A30 [[English Opening#1...c5|English, Symmetrical]]
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| Peter Svidler (5) || Levon Aronian (5½) ||align=center | ½–½ || A07 [[King%27s_Indian_Attack's Indian Attack#Barcza_SystemBarcza System|King's Indian Attack]]
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| Vladimir Kramnik (4½) || Viswanathan Anand (6½) ||align=center | ½–½ || E06 [[Catalan Opening|Catalan Opening, Closed, 5.Nf3]]
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|colspan=4 bgcolor="#cccccc" | '''Round 12 – 27 March 2014'''
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| Viswanathan Anand (7) || Dmitry Andreikin (5) ||align=center | ½–½ || B18 [[Caro–Kann Defence#Classical Variation: 4...Bf5|Caro-Kann, Classical]]
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| Shakhriyar Mamedyarov (5½) || Sergey Karjakin (5½) ||align=center | ½–½ || E20 [[Nimzo-Indian]]
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| Veselin Topalov (4½) || Peter Svidler (5½) ||align=center | 1–0 || B49 [[Sicilian Defence#Taimanov Variation: 4...Nc6|Sicilian Defence, Taimanov Varation]]
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| Levon Aronian (6) || Vladimir Kramnik (5) ||align=center | ½–½ || D36 [[Queen's Gambit Declined]]
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|colspan=4 bgcolor="#cccccc" | '''Round 13 – 29 March 2014'''
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| Dmitry Andreikin (5½) || Levon Aronian (6½) ||align=center | –
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| Sergey Karjakin (6) || Viswanathan Anand (7½) ||align=center | –
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| Peter Svidler (5½) || Shakhriyar Mamedyarov (6) ||align=center | –
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| Vladimir Kramnik (5½) || Veselin Topalov (5½) ||align=center | –
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|colspan=4 bgcolor="#cccccc" | '''Round 14 – 30 March 2014'''
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| Levon Aronian || Sergey Karjakin ||align=center | –
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| Viswanathan Anand || Peter Svidler ||align=center | –
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| Shakhriyar Mamedyarov || Vladimir Kramnik ||align=center | –
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| Veselin Topalov || Dmitry Andreikin ||align=center | –
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