Azido maliko: berrikuspenen arteko aldeak

Ezabatutako edukia Gehitutako edukia
t Autoritate kontrola jartzea
t Robota: Testu aldaketa automatikoa (-\{\{(.*\n)*\}\}\n\n\'\'\' +{{konposatu kimiko infotaula}}\n''')
1. lerroa:
{{konposatu kimiko infotaula}}
{{chembox
| verifiedrevid = 447048636
| Name = Azido maliko
| ImageFile = Äpfelsäure3.svg
| ImageSize = 180px
| ImageName = Skeletal structure
| ImageFile1 = Malic-acid-3D-balls.png
| ImageName1 = Ball-and-stick model
| ImageFile2 = Sample of racemic malic acid.jpg
| ImageSize2 = 250px
| ImageCaption2 = <sub>DL</sub>-Malic acid
| IUPACName = azido hydroxibutanedioiko
| OtherNames = Azido <small>L</small>-Maliko<br />Azido <small>D</small>-Maliko<br />Azido (–)-Maliko<br />Azido (+)-Maliko<br />Azido (''S'')-hidroxibutanedioiko<br />Azido (''R'')-hidroxibutanedioiko
| Section1 = {{Chembox Identifiers
| PubChem = 525
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 817L1N4CKP
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG = C00149
| ChEMBL = 1455497
| InChI = 1/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)
| InChIKey = BJEPYKJPYRNKOW-UHFFFAOYAM
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 6650
| SMILES = O=C(O)CC(O)C(=O)O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = BJEPYKJPYRNKOW-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 617-48-1
| CASNo = 6915-15-7
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 510
| ChemSpiderID1_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID1=83793
| ChemSpiderID1_Comment = D-(+)-malic acid
| ChemSpiderID2_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID2 = 193317
| ChemSpiderID2_Comment = L-(-)-malic acid
| EINECS = 230-022-8
| CoE = 17
| FEMA = 2655
| JECFA = 619
}}
| Section2 = {{Chembox Properties
| C=4 | H=6 | O=5
| MeltingPtC = 130
| Density = 1.609 g cm<sup>−3</sup>
| pKa = p''K''<sub>a1</sub> = 3.40, p''K''<sub>a2</sub> = 5.20 <ref>Dawson, R. M. C. et al., ''Data for Biochemical Research'', Oxford, Clarendon Press, 1959.</ref>
| Solubility = 558 g/L (20&nbsp;°C-tan)<ref>[http://chemblink.com/products/6915-15-7.htm chemBlink Online Database of Chemicals from Around the World]</ref>
}}
| Section4 = {{Chembox Related
| OtherAnions = [[malato]]
| Function = [[Azido karboxiliko]]ak
| OtherFunctn = [[azido sukziniko]]<br />[[azido tartariko]]<br />[[azido fumariko]]
| OtherCpds = [[1-butanol|butanol]]<br />[[butiraldehido]]<br />[[Krotonaldehido]]<br />[[sodio malato]]
}}
}}
 
'''Azido maliko''' (HO<sub>2</sub>CCH<sub>2</sub>CHOHCO<sub>2</sub>H) landare eta fruitu ugaritan –[[sagar]] berdeetan, batik bat– izaten den bi azidodun [[alkohol]]a da. Landareen eta animalien zelulen metabolismoan parte hartzen du. 100&nbsp;°C–tan urtzen diren kristalak eratzen ditu, eta uretan eta alkoholean urtzen da. Sintesiz ere lor daiteke, [[azido maleiko]]a berotuz, edo [[azido tartariko]]tik, [[azido sukziniko|sukzinikotik]] eta [[azido aspartiko|aspartikotik]].